| 09.08.2013 Friday |
 | Metalurh Z | | 2:2 | | Sevastopol | |
| Referee: Anatolii Abdula - Stadion: "Slavutych-Arena", Zaporizhzhia |
| 10.08.2013 Saturday |
| Vorskla | | 1:0 | | Illichivets | |
| Referee: Ivan Bondar - Stadion: "Vorskla" n.a. Oleksii Butovskyi, Poltava |
|
| Karpaty | | 0:0 | | Zoria | |
| Referee: Anatolii Zhabchenko - Stadion: "Ukraine", Lviv |
|
| Tavriia | | 0:4 | | Shakhtar | |
| Referee: Serhii Berezka - Stadion: , Simferopol |
|
| Metalist | | 4:0 | | Volyn | |
| Referee: Serhii Boiko - Stadion: RSC "Metalist", Kharkiv |
| 11.08.2013 Sunday |
| Dnipro | | 1:0 | | Hoverla | |
| Referee: Oleksandr Derdo - Stadion: "Dnipro-Arena", Dnipropetrovsk |
|
| Metalurh D | | 2:0 | | Arsenal | |
| Referee: Kostiantyn Trukhanov - Stadion: "Metalurh", Donetsk |
|
| Dynamo | | 1:2 | | Chornomorets | |
| Referee: Yurii Mozharovskyi - Stadion: NSC "Olimpiiskyi", Kyiv |