| 11.05.2014 Sunday |
 | Volyn | | 1:2 | | Sevastopol | |
| Referee: Oleksandr Derdo - Stadion: "Avanhard", Lutsk |
|
| Zoria | | 1:3 | | Shakhtar | |
| Referee: Yevhen Aranovskyi - Stadion: "Central stadium", Cherkasy |
|
| Hoverla | | 1:1 | | Chornomorets | |
| Referee: Serhii Berezka - Stadion: "Avanhard", Uzhgorod |
|
| Metalurh D | | 2:0 | | Metalurh Z | |
| Referee: Serhii Dankovskyi - Stadion: "Meteor", Dnipropetrovsk |
|
| Illichivets | | 0:2 | | Dynamo | |
| Referee: Anatolii Zhabchenko - Stadion: NSC "Olimpiiskyi", Kyiv |
|
| Karpaty | | 2:4 | | Metalist | |
| Referee: Serhii Boiko - Stadion: "Ukraine", Lviv |
|
| Vorskla | | 1:4 | | Dnipro | |
| Referee: Yurii Moseichuk - Stadion: "Vorskla" n.a. Oleksii Butovskyi, Poltava |