| 19.04.2014 Saturday |
 | Hoverla | | 1:2 | | Illichivets | |
| Referee: Yurii Mozharovskyi - Stadion: "Avanhard", Uzhgorod |
|
| Shakhtar | | 2:1 | | Metalurh D | |
| Referee: Viktor Shvetsov - Stadion: "Donbas Arena", Donetsk |
| 20.04.2014 Sunday |
| Tavriia | | 14:00 | | Karpaty | |
| Referee: Oleksandr Ivanov - Stadion: "Lokomotyv", Simferopol |
|
| Volyn | | 15:00 | | Zoria | |
| Referee: Yaroslav Kozyk - Stadion: "Avanhard", Lutsk |
|
| Metalurh Z | | 17:00 | | Metalist | |
| Referee: Serhii Boiko - Stadion: "Slavutych-Arena", Zaporizhzhia |
|
| Dynamo | | 17:00 | | Vorskla | |
| Referee: Kostiantyn Trukhanov - Stadion: NSC "Olimpiiskyi", Kyiv |
|
| Chornomorets | | 19:30 | | Dnipro | |
| Referee: Anatolii Zhabchenko - Stadion: "Chornomorets", Odesa |